検索結果- 英語 - 英語
検索内容:
di-pimethane rearrangement
noun
A
photochemical
reaction
of
a
molecular
entity
comprising
two
p-systems,
separated
by
a
saturated
carbon
atom
(a
1,4-diene
or
an
allyl-substituted
aromatic
analog),
to
form
an
ene-
(or
aryl-)
substituted
cyclopropane.
The
rearrangement
formally
amounts
to
a
1,2
shift
of
one
ene
group
(in
the
diene)
or
the
aryl
group
(in
the
allyl-aromatic
analog)
and
‘bond
formation’
between
the
lateral
carbons
of
the
non-migrating
moiety.
Kornblum-DeLaMare rearrangement
noun
rearrange the deck chairs on the Titanic
verb
rearranges the deck chairs on the Titanic
verb