最終更新日:2024/08/07
(chemistry) A palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product.
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Tsuji-Trost reaction
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Tsuji-Trost reaction
noun
(chemistry)
A
palladium-catalysed
substitution
reaction
involving
a
substrate
that
contains
a
leaving
group
in
an
allylic
position.
The
palladium
catalyst
first
coordinates
with
the
allyl
group
and
then
undergoes
oxidative
addition,
forming
the
π-allyl
complex.
This
allyl
complex
can
then
be
attacked
by
a
nucleophile,
resulting
in
the
substituted
product.
意味(1)
(chemistry)
A
palladium-catalysed
substitution
reaction
involving
a
substrate
that
contains
a
leaving
group
in
an
allylic
position.
The
palladium
catalyst
first
coordinates
with
the
allyl
group
and
then
undergoes
oxidative
addition,
forming
the
π-allyl
complex.
This
allyl
complex
can
then
be
attacked
by
a
nucleophile,
resulting
in
the
substituted
product.