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glyoxalase
noun
(biochemistry)
Either
of
a
pair
of
related
thiol-dependent
enzymes:
glyoxalase
І,
which
catalyses
the
isomerisation
of
the
spontaneously
formed
hemithioacetal
adduct
between
GSH
and
2-oxoaldehydes
(such
as
methylglyoxal)
into
S-2-hydroxyacylglutathione;
and
glyoxalase
ІІ,
which
hydrolyses
these
thiolesters.
